The 5.45pm GMT kick-off against the Spanish side at Estadi Montilivi will be shown live on TNT Sports in the UK. For global broadcast listings, go here.
Get fixture and broadcast information directly to your phone by downloading our eCalendarhere
Matchday Live begins at 4.30pm GMT on LFCTV, with build-up followed by live audio commentary and then post-match reaction from the stadium.
Free live audio commentary for this game is also available at video.liverpoolfc.com and in our dedicated Match Centre.
Follow Match Centre on Liverpoolfc.com and the official LFC app [iOS| Google Play] from 12pm GMT on Tuesday for live build-up, confirmed team news, minute-by-minute updates, photos, videos, post-match reaction and more.
Goals, highlights, a full match replay and much more from the game will be available for subscribers on LFCTV GO from midnight GMT.