Holders Paris scored seven on Tuesday night to move top of the UEFA Champions League standings on a perfect nine points, a feat also achieved by Inter and Arsenal following convincing wins of their own. Barcelona and PSV, meanwhile, scored six on a night which threw up a remarkable 43 goals in all.
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Tuesday night's action
Leverkusen 2-7 Paris
A stunning attacking display powered Paris to a commanding victory at the BayArena, with Ousmane Dembélé's scoring return from injury helping to ice the cake.
A manic first half saw both teams reduced to ten men, but it was the visitors who had over 70% of the possession and subsequently controlled the game. First, Willian Pacho netted his first goal for the club, before Désiré Doué then struck either side of Khvicha Kvaratskhelia's effort. Nuno Mendes, Dembélé and Vitinha got in on the act in the second half, with Aleix García's double providing the hosts with a consolation.
Player of the Match: Nuno Mendes (Paris)
Matchday 4 04/11: Paris vs Bayern München
05/11: Benfica vs Leverkusen
Barcelona 6-1 Olympiacos
Fermín López hit a hat-trick as Barcelona earned an emphatic first home win.
The Spain winger's composed finishes gave the hosts a 2-0 half-time advantage before Ayoub El Kaabi replied with a penalty for Olympiacos, who had Santiago Hezze dismissed for a second caution soon afterwards.
Lamine Yamal’s spot kick proved the first of four goals in 13 minutes for rampant Barça, Fermín López completing his treble in between two Marcus Rashford strikes as the five-time champions reached six points.
Player of the Match: Fermín López (Barcelona)
Matchday 4
04/11: Olympiacos vs PSV
05/11: Club Brugge vs Barcelona
Arsenal 4-0 Atleti
Arsenal continued their winning start to the Champions League campaign with a statement 4-0 victory over Atleti.
Both sides struck the woodwork before Gabriel headed Declan Rice's free-kick in to give the hosts the advantage shortly before the hour mark.
Three further goals followed in the next 13 minutes, as Gabriel Martinelli curled into the corner before Viktor Gyökeres' double added extra gloss to the scoreline.
Player of the Match: Viktor Gyökeres
Matchday 4
04/11: Slavia Praha vs Arsenal (18:45)
04/11: Atleti vs Union SG
Kairat Almaty 0-0 Pafos
Ten-man Pafos claimed their second point of the league phase in this entertaining contest in Almaty.
The visitors regrouped after being reduced to ten men in the fourth minute following João Correia's dismissal and almost edged in front in the second half, with Temirlan Anarbekov producing two smart saves to deny David Luiz following set-piece deliveries.
The hosts piled forward as the contest wore on, with Giorgi Zaria testing Neofytos Michael and Ofri Arad hitting the inside of a post, but neither side could find the goal to secure their first win in the competition proper.
Player of the Match: David Luiz (Pafos)
Matchday 4
05/11: Pafos vs Villarreal (18:45)
05/11: Inter vs Kairat Almaty
Copenhagen 2-4 B. Dortmund
Felix Nmecha scored twice as Dortmund maintained their unbeaten start with a 4-2 victory over Copenhagen.
Nmecha drilled the visitors ahead in the 20th minute, though Waldemar Anton's own goal levelled things at half-time.
Ramy Bensebaini restored Dortmund's lead from the penalty spot just after the hour, before Nmecha fired in his second of the game.
Fábio Silva added a fourth goal from a tight angle, with Viktor Daðason heading in a stoppage-time consolation for the hosts.
Matchday 4
04/11: Tottenham vs Copenhagen05/11: Man City vs B. Dortmund
Newcastle 3-0 Benfica
Newcastle made it back-to-back wins after coming out on top in a pulsating encounter at St James' Park against a Benfica team who remain without a point in the league phase.
Chances flowed in the first half, including a thumping Dodi Lukébakio strike off a post, but it was Anthony Gordon who broke the deadlock with his fourth goal of the campaign to finish a lovely move.
Harvey Barnes came off the bench to double the advantage, running onto a long throw by goalkeeper Nick Pope, and then settled things with a third after being set up by Gordon.
Matchday 4
05/11: Newcastle vs Athletic Club05/11: Benfica vs Leverkusen
PSV 6-2 Napoli
PSV got their league phase campaign up and running with a convincing win against Napoli in Eindhoven.
Scott McTominay headed the visitors in front before an Alessandro Buongiorno own goal and Ismael Saibari strike gave PSV the lead at the break. A Dennis Man double, including a spectacular second, asserted their dominance after Lorenzo Lucca saw red for Napoli.
McTominay got a second late on but PSV hit back through Ricardo Pepi and then Couhaib Driouech to put the seal on a memorable evening.
Matchday 4
04/11: Olympiacos vs PSV04/11: Napoli vs Frankfurt (18:45)
Union SG 0-4 Inter
Inter withstood an abundance of early pressure to stay perfect in style.
Christian Burgess had a shot cleared off the line and Promise David and Mathias Rasmussen tested goalkeeper Yann Sommer during a blistering start by Union, but Denzel Dumfries lashed in following a corner before Lautaro Martínez curled in the visitors' second.
Hakan Çalhanoğlu added a penalty after the restart and Pio Esposito then slotted in his first Champions League goal, ensuring the Belgian club remain on three points.
Matchday 4
04/11: Atleti vs Union SG05/11: Inter vs Kairat Almaty
Villarreal 0-2 Man City
Erling Haaland's neat finish and Bernardo Silva's powerful header helped the visitors end a five-match winless run on the road in this competition.
Haaland took just 17 minutes to strike for a 12th successive match for club and country, guiding in a neat finish from Rico Lewis' clever pass.
Captain Bernardo Silva doubled the advantage with half-time approaching, nodding in emphatically from Savinho's pinpoint cross.
Villarreal went closest to reducing the deficit late on, but substitute Tani Oluwaseyi was denied by the woodwork.
Matchday 4
05/11: Pafos vs Villarreal (18:45) 05/11: Man City vs B. Dortmund
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