Albion will be ball 11 when the draw for the third round of the Carabao Cup takes place on Wednesday.
It will be broadcast on Sky Sports at the conclusion of the Preston v Everton tie.
The draw will include 32 clubs – 23 winners from round two and the nine Premier League clubs competing in UEFA competitions.
Draw conditions will only be required for the eight clubs playing in the UEFA Champions League and the UEFA Europa League, due to their European fixtures falling between the same two-week period as Round Three.
Albion may also enter UEFA competition through the Conference League, but that competition does not begin until October, so it does not affect the Round Three schedule.
Before the main draw, there will be a pre-draw (approx. 7:15pm) to decide whether each of the eight Champions League and Europa League Clubs will be at home or away.
In the main draw (approx. 10:20pm) the first eight ties will involve those Champions League and Europa League clubs, with their home or away position already having been decided, and each will be drawn against a club from a separate bowl containing the remaining teams. Once those eight ties have been drawn, the final eight ties will be drawn as normal.
1 AFC Bournemouth
2 Arsenal
3 Aston Villa
4 Crystal Palace
5 Manchester City
6 Manchester United
7 Liverpool
8 Sunderland
9 Barnsley
10 Brentford
11 Brighton & Hove Albion
12 Coventry City
13 Fleetwood Town
14 Hull City
15 Ipswich Town
16 Leeds United
17 Leyton Orient
18 Lincoln City
19 Middlesbrough
20 Millwall
21 Norwich City
22 Peterborough United
23 Reading
24 Sheffield United
25 West Ham United
26 Wolverhampton Wanderers
27 Bradford City / Burnley
28 Newcastle United / West Bromwich Albion
29 Tottenham Hotspur / Charlton Athletic
30 Preston North End / Everton
31 Chelsea / Luton Town
32 Fulham / AFC Wimbledon